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Carbonate · Hydroxylated carbonate · Malachite Group

Malachite

Cu₂(CO₃)(OH)₂

The banded green copper carbonate — soft enough to carve, vivid enough for a pharaoh's eyeshadow, and fizzy enough to identify with a drop of acid.

Hardness3.5–4
Crystal systemMonoclinic
LusterAdamantine to vitreous
Sp. gravity3.6–4.05
ClassCarbonate
Malachite specimen

Banded malachite — concentric green rings in a polished stalactite cross-section — Photo: Steve Jurvetson · CC BY 2.0

What is Malachite?

Malachite is a copper carbonate hydroxide — Cu₂(CO₃)(OH)₂ — and one of the most instantly recognizable minerals on Earth. That saturated green, usually arranged in sweeping bands of light and dark, has been mined, carved and ground into pigment for at least 6,000 years.

It is a secondary mineral: it forms when oxygen-rich rainwater and carbonate-bearing groundwater attack copper sulfides near the surface. Almost every copper deposit hosts some malachite in its weathered zone, often growing over — or completely replacing — its blue sibling azurite. Intergrowths of the two are sold as ‘azur-malachite’.

Malachite was once a serious ore of copper; today most of it goes to collectors and lapidaries. It is soft enough to carve yet takes a fine polish, which is why palace rooms, jewelry boxes and green oil paint have all been made from it.

In one sentence: Malachite is always green, usually banded, softer than glass, and it effervesces in acid. Slice a stalactite across and you get the famous bull's-eye rings.

Physical Properties

The full data table is in the panel alongside. Here’s what those numbers actually mean.

Color and banding. The green comes from copper itself — an intrinsic, unchanging ingredient — so malachite never fades. Concentric bands record rhythmic changes in copper supply as the mineral grew layer by layer in open cavities.

Hardness and weight. At Mohs 3.5–4 it scratches easily (a copper coin marks it), yet it is surprisingly dense — around SG 3.6–4 — because of all that copper. A fist-sized lump feels heavier than it looks.

The fizz. Drop dilute hydrochloric acid (or strong vinegar, given time) on malachite and it bubbles: the carbonate group is releasing carbon dioxide. That test separates it from every green lookalike that isn't a carbonate.

Habit. Well-formed crystals are rare; the typical look is botryoidal — globular, grape-like crusts — or stalactitic columns and velvety fibrous coatings. Polished slabs show the banding best.

How & Where It Forms

Malachite crystallizes in the oxidized zone of copper deposits, where sulfides such as chalcopyrite and bornite break down and the released copper meets carbonate-rich groundwater. It coats fractures, fills cavities as stalactites, and cements gravel into ‘copper sand’.

It is famously unstable-relative: azurite alters to malachite as conditions become wetter, so nature produces pseudomorphs — malachite keeping the sharp shape of a vanished azurite crystal. The great masses of Katanga and the Urals formed where huge sulfide bodies weathered for millions of years.

Often grows alongside:

What It’s Used For

Copper oreOne of humanity's first copper sources — mined since the Bronze Age at Timna, Cyprus and Sinai.
Ornamental stone & jewelryBanded slabs are cut into cabochons, beads, boxes and columns — the Hermitage's Malachite Room is lined with it.
PigmentGround malachite was the green in Egyptian eye-paint and Renaissance paintings before synthetic pigments.
Collector specimensVelvety botryoidal crusts and stalactite cross-sections are staples of every collection.

How to Identify It

Green + banded + fizzing in acid is essentially diagnostic. Check that the color is a saturated green (not blue-green like chrysocolla), that it scratches with a knife (H ~4), and that a drop of acid bubbles. Intergrowth with azurite clinches it.

Vivid green with light-and-dark bandingFizzes in dilute acid — it's a carbonateSofter than glass (H 3.5–4), pale green streakHeavier than it looks (SG ~3.6–4)Often intergrown with deep-blue azurite
Looks like…But differs because…Quick test
ChrysocollaBlue-green and botryoidal or earthy rather than sharply banded; never effervescesAcid test
BrochantiteA copper sulfate, usually darker emerald-green needles or crusts; no fizzAcid test
PseudomalachiteCopper phosphate of deeper, more uniform green; does not effervesceAcid test
SmithsoniteCan be apple-green but is harder (4–4.5) and forms rounded 'cobbled' crustsHardness
DioptaseHarder (5), trigonal emerald-green crystals, no effervescenceAcid & crystal form

Where It’s Found

Notable localities for fine specimens:

References & Further Reading

  1. Dana's New Mineralogy, 8th ed. Hydroxyl carbonates.
  2. Mindat.org — Malachite mineral data and locality records.
  3. Wikipedia — Malachite.

Last reviewed 2026-09-14 · How to cite this page.