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Halide · Simple anhydrous halide · Fluorite Group

Fluorite

CaF₂

The most colorful mineral on Earth — glassy glowing cubes that gave fluorescence its name and give industry its fluorine.

Hardness4
Crystal systemCubic
LusterVitreous
Sp. gravity3.17–3.18
ClassHalide
Fluorite specimen

Purple fluorite cubes — the classic habit of the world’s most colorful mineral — Photo: Amy M Lavine · CC BY-SA 4.0

What is Fluorite?

Fluorite is calcium fluoride — CaF₂ — a soft, glassy mineral famous for two things: an astonishing range of colors and a literal glow. Under ultraviolet light many specimens shine violet-blue; the phenomenon fluorescence was named after this mineral.

It crystallizes as perfect cubes — sometimes two cubes interpenetrating like a three-dimensional star — and it cleaves into octahedra, so the ‘fluorite octahedrons’ sold in gift shops are cleaved, not cut. Colors run from purple and green to yellow, blue and colorless, often banded within a single crystal; Derbyshire’s purple-and-white banded variety is the prized Blue John.

Fluorite is also an industrial workhorse: as fluorspar it is the world’s main source of fluorine for hydrofluoric acid, refrigerants and PTFE, and a flux in steelmaking.

In one sentence: Look for cubes or octahedra, a glassy shine, hardness 4 (a knife scratches it), perfect cleavage in four directions — then check whether it glows under a UV lamp.

Physical Properties

The full data table is in the panel alongside. Here’s what those numbers actually mean.

Octahedral cleavage. Fluorite splits perfectly along four directions, yielding eight-sided octahedra. Tap a cube just right and it breaks into smaller octahedra — a signature no common lookalike shares.

Fluorescence. Many specimens glow blue or violet in UV light, and some change color between shortwave and longwave lamps. A few (‘chlorophane’) glow faintly green when simply warmed in the hand.

Color. No mineral shows a wider natural palette. The colors come from trace rare-earth elements, radiation-induced color centers and microscopic inclusions — often laid down in bands that record the chemistry of each growth stage.

Softness. Fluorite is the Mohs 4 standard: a steel knife scratches it, but a fingernail and a copper coin do not.

How & Where It Forms

Fluorite precipitates from fluorine-bearing hydrothermal fluids, filling veins and fissures — often alongside the lead and zinc sulfides galena and sphalerite. The great Mississippi Valley-type deposits of Illinois and Kentucky formed exactly this way, as warm brines moved through limestone.

It also occurs in granites, greisens and pegmatites, and around hot springs. Sharp crystals need open space, so the finest pockets come from vein cavities where cubes could grow freely.

Often grows alongside:

What It’s Used For

Metallurgical fluxAs ‘fluorspar’ it lowers the melting point of slag in steel and aluminium smelting — hence the name, from Latin ‘to flow’.
Hydrofluoric acidNearly all fluorine chemistry — refrigerants, PTFE, pharmaceuticals, uranium processing — starts with acid-grade fluorite.
OpticsLow-dispersion fluorite elements sharpen the images of telescopes, microscopes and camera lenses.
Carving & gemsBanded material like Blue John is carved into ornaments; crystals are cut for collectors — too soft for everyday rings.

How to Identify It

Hardness 4 plus four-way octahedral cleavage is decisive: scratch it with a knife, then look for flat faces meeting in octahedral geometry. Glassy cubes in purple or green are typical, and a UV lamp usually settles it — fluorite fluoresces where quartz and beryl do not. It never fizzes in acid, which separates it from calcite at a stroke.

Perfect octahedral cleavage — splits into eight-sided piecesHardness 4 — a knife scratches it, a coin doesn’tOften fluoresces blue-violet under UVCubic crystals, sometimes two cubes intergrownDoes not fizz in acid
Looks like…But differs because…Quick test
QuartzFar harder (7) with no cleavage; crystals are six-sided prismsKnife test
CalciteSofter (3), cleaves into rhombs not octahedra, and fizzes in acidDrop of vinegar
ApatiteHarder (5), grows as six-sided prisms and lacks perfect cleavageScratch & shape
BerylMuch harder (7.5–8), hexagonal prisms, no octahedral cleavageHardness

Where It’s Found

Notable localities for fine specimens:

References & Further Reading

  1. Dana’s New Mineralogy, 8th ed. Simple halides, fluorite group.
  2. Mindat.org — Fluorite mineral data and locality records.
  3. Wikipedia — Fluorite.

Last reviewed 2026-09-14 · How to cite this page.